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61.
Silver nanoparticles immobilized onto poly(4‐vinylpyridine)‐functionalized magnetic nanoparticles: A robust magnetically recyclable catalyst for oxidant‐free alcohol dehydrogenation 下载免费PDF全文
A heterogeneous and recyclable catalyst with a high loading of silver nanoparticles was synthesized via the silver nanoparticles being supported onto the surface of magnetic nanoparticles coated with poly(4‐vinylpyridine). The synthesized catalyst was used in the dehydrogenation of alcohols to corresponding carbonyl compounds. A broad diversity of alcohols was converted into their corresponding carbonyl compounds in excellent yields. The catalyst was easily recovered by applying an external magnetic field and reused for seven reaction cycles without considerable loss of activity. The catalyst was fully characterized using various techniques. 相似文献
62.
It is described a simple, rapid and efficient methodology to characterise and separate gold nanoprisms and nanooctahedra by capillary electrophoresis. This technique is suitable to distinguish between morphologies and it can be used as a powerful separation tool after a customised synthesis of both structures. This synthesis was carried out by amending two parameters, temperature and pH, and a sharp decrease was found in nanotriangles when temperature was increased from 70 up to 95°C. However, when the synthesis was performed at a given temperature, an increase in pH did not promote an important change in isolation of any structure until pH = 9.5, critical in the final morphology of the nanoparticle. Gold nanoprisms and nanooctahedra were successfully separated by capillary electrophoresis according to differences in charge‐to‐mass ratio of the morphologies. Final particle morphology was confirmed by transmission electron microscopy analysis. Under optimal working conditions, a mixture containing both shapes of gold nanoparticles was initially injected and two major peaks were obtained for each structure. Capillary electrophoresis allowed to study pH and temperature influence on both morphologies. It was inferred that the ratio between triangles and octahedra decreased to a great extent when increasing both temperature and pH. 相似文献
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65.
Saleh Mohammed Mokbel E. N. Kolosov I. I. Mikhalenko 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(6):1289-1292
A comparative study of oxidation of phenol, 3-chlorophenol, 4-chlorophenol, and 2,4-dichlorophenol on Pt/Ti and Ce,Pt/Ti electrocatalysts is performed via cyclic voltammetry. It is shown that the surface morphology and roughness of the anode do not change after modification with cerium. The formal kinetic orders of electrooxidation of all compounds are found to be less than one. It is shown that the β temperature coefficients of the rate of oxidation of chlorophenols grow by 10 to 50% when the Ce,Pt/Ti anode is used at a substrate concentration of 1 mM. A tenfold increase in concentration reduces the effect of cerium additive, except for 3-chlorophenol: the latter exhibits a 250% increase in the β value, compared to the Pt/Ti anode. 相似文献
66.
Long Yuan Mohammed Jemal Anne‐Francoise Aubry 《Rapid communications in mass spectrometry : RCM》2012,26(12):1465-1474
67.
In this paper, we establish the existence of multiple solutions for nonhomogeneous singular elliptic equations with cylindrical weights, by using Ekeland??s variational principle and mountain pass theorem without Palais?CSmale condition. 相似文献
68.
In this paper,we study the surface instability of a cylindrical pore in the absence of stress. This instability is called the Rayleigh-Plateau instabilty. We consider the model developed by Spencer et ... 相似文献
69.
Dolores Bellido-Milla Laura Ma Cubillana-Aguilera Mohammed El Kaoutit Ma Purificación Hernández-Artiga José Luis Hidalgo-Hidalgo de Cisneros Ignacio Naranjo-Rodríguez José Ma Palacios-Santander 《Analytical and bioanalytical chemistry》2013,405(11):3525-3539
Graphite powder-based electrodes have the electrochemical performance of quasi-noble metal electrodes with intrinsic advantages related to the possibility of modification to enhance selectivity and their easily renewable surface, with no need for hazardous acids or bases for their cleaning. In contrast with commercial electrodes, for example screen-printed or sputtered-chip electrodes, graphite powder-based electrodes can also be fabricated in any laboratory with the form and characteristics desired. They are also readily modified with advanced materials, with relatively high reproducibility. All these characteristics make them a very interesting option for obtaining a large variety of electrodes to resolve different kinds of analytical problems. This review summarizes the state-of-the-art, advantages, and disadvantages of graphite powder-based electrodes in electrochemical analysis in the 21st century. It includes recent trends in carbon paste electrodes, devoting special attention to the use of emergent materials as new binders and to the development of other composite electrodes. The most recent advances in the use of graphite powder-modified sol–gel electrodes are also described. The development of sonogel–carbon electrodes and their use in electrochemical sensors and biosensors is included. These materials extend the possibilities of applications, especially for industrial technology-transfer purposes, and their development could affect not only electroanalytical green chemistry but other interesting areas also, for example catalysis and energy conversion and storage. 相似文献
70.
Colorimetric and Spectrofluorimetric Methods for the Determination of Melatonin in Tablets and Serum
Abstract Two sensitive and accurate colorimetric and spectrofluonmetric methods, are presented for the determination of melatonin in tablets and serum. The first method utilizes the reactions of p-dimethylaminobenzaldehyde in hydrochloric acid (van Urk reagent)-ferric chloride in sulphuric acid (Salkowski reagent) mixture. The blue color of the resulting reaction product is measured at 630 nm. The second method is based on the reaction of melatonin with o-phthalaldehyde in acid medium which yields highly fluorescent condensation product that is measured at 465 nm as emission wavelength, using excitation wavelength at 355 nm. No interference was observed from tableting additives, and the applicability of the methods was examined by analysing tablets containing melatonin (single and combined with pyridoxine). Mean percentage recoveries from tablets were found to be 99.9+0.31 for single and 100.5+0.15 for combined tablets using colorimetric method, while by applying spectrofluorimetric method the recoveries were found to be 100.610.41 for single and 100.2+0.39 for combined tablets. Furthermore, the proposed methods were extended to the in-vitro determination of melatonin in serum. The detection limits are 0.27 ug ml?1 for colorimetric method and 0.00035 ug ml?1 for spectrofluorimetric method. 相似文献